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Silver Ion-Assisted Ring Expansions in Different Solvent Systems
Carbene bicyclic compound ring opening ring expansion vinylic halide
2010/4/9
Several ring expansion products carrying vinylic bromo functionality were synthesized by opening of the geminal dibromobicyclo[n.1.0]alkanes ring. Dibromocarbene was formed from bromoform and potassiu...
New Aspects in the Chemistry of Three-membered Ring Compounds Containing a Highly Coordinate Main Group Element
Martin ligan P-chalcogen bon three-membered ring compoun
2007/12/19
摘要 The title compounds were synthesized by taking advantage of the Martin ligand. Their structures were determined by X-ray crystallography. Pentacoordinate thiasiliranides were hydrolyzed to give the...