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Temperature Dependence of the Electric Field Modulation of Electron-Transfer Rates:Charge Recombination in Photosynthetic Reaction Centers
solar energy inorganic, organic, physical and analytical chemistry photosynthesis reaction kinetics electric fields electron transfer entropy experimental data free energy mathematical models
2016/5/23
The rates of electron-transfer reactions can be systematically varied by application of external electric fields. The electric field effect on the charge recombination rate constant of the state P[sup...
Electric Field Modulation of Electron Transfer Reaction Rates in Isotropic Systems:Long-Distance Charge Recombination in Photosynthetic Reaction Centers
CORROSION PRODUCT NICKEL FERRITE MAGNETITE PH SOLUBILITY PWR STEAM GENERATORS
2016/5/23
A general method is demonstrated for experimentally obtaining the rate constant of electron transfer as a function of the free energy of the reaction in nonoriented systems. An external electric field...
Scaling Relations and Optimization of Excitonic Energy Transfer Rates between One-Dimensional Molecular Aggregates
Scaling Relations Optimization of Exciton Energy Transfer Rates One-Dimensional Molecular Aggregates
2014/9/24
We theoretically study the distance, chain length, and temperature dependence of the electronic couplings as well as the excitonic energy transfer rates between onedimensional (1D) chromophore aggrega...
Universal ultracold collision rates for polar molecules of two alkali-metal atoms
Physical Chemistry Chemical Physics cold molecules
2011/8/29
Universal collision rate constants are calculated for ultracold collisions of two like bosonic or fermionic heteronuclear alkalimetal dimers involving the species Li, Na, K, Rb, or Cs. Universal colli...
High Rates of Fluorescence Quenching Between Perylene Dodecyldiimide and Certain p-Electron Donors
High Rates Fluorescence Quenching Between Perylene Dodecyldiimide and Certain p-Electron Donors
2010/8/19
Perylene bis-n-dodecyl diimide is found to quench fluorescenc emissions of naphthalene, phenanthrene and dihydrocarbazolocarbazole molecules at rates of 4.4\times1011, 2.8\times1012 and 2.5\times104 M...
The computation of electron transfer rates: The nonadiabatic instanton solution
electron transfer rates nonadiabatic instanton
2014/9/24
A computational theory for determining electron transfer rate constants is formulated based on an instanton expression for the quantum rate and the self-consistent solution of the imaginary time nonad...
