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Nonphotochemical Holeburning in a Protein Matrix: Chlorophyllide in Apomyoglobin
Proteins Polymers Temperature measurement Amorphous metals Dephasing
2016/5/20
Nonphotochemical holeburning spectroscopy has been used to study a chlorophyllide chromophore substituted for heme in apomyoglobin. The observed holewidths were compared with those found for the same ...
Excitation Transport and Trapping in a Synthetic Chlorophyllide Substituted Hemoglobin:The Orientation of the Chlorophyll S1 Transition Dipole
Excitation Transport Synthetic Chlorophyllide Substituted Hemoglobin Chlorophyll S1 Transition Dipole
2016/5/20
Excitation transport in synthetic zinc chlorophyllide substituted hemoglobin has been observed by picosecond time-resolved fluorescence depolarization experiments.In this hybrid molecular system, two ...
Chlorophyllide-substituted Hemoglobin Tetramers and Hybrids:Preparation,Properties and Energy Transfer
Chlorophyllide Hemoglobin Tetramers Hybrids Preparation Properties Energy Transfer
2016/5/20
Three chlorophyllide-substitutedhuman hemoglobin (Hb) complexes have been prepared: the tetrameric complex in which zinc pyrochlorophyllide a (ZnPChla) is substituted for all four hemes and the two co...
Solution Properties of Synthetic Chlorophyllide-and Bacteriochlorophyllide-apomyoglobin Complexes
Solution Properties Chlorophyllide Bacteriochlorophyllide apomyoglobin Complexes
2016/5/20
Well-defined 1:1 complexes have been formed between apomyoglobin (apoMb) and a number of chlorophyllide derivatives. The chlorophyllides substitute for heme in the pocket of myoglobin. These include m...
Preparation and Properties of a Chlorophyllide-Apomyoglobin Complex
Preparation Properties Chlorophyllide-Apomyoglobin Complex
2016/5/20
The spectroscopy of large molecules like chlorophyll poses a number of problems because it is difficult to obtain a transparent host matrix for single-crystal optical and magnetic resonance investigat...