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Isoprene is the most abundant non-methane biogenic volatile organic compound (BVOC), but the processes governing secondary organic aerosol (SOA) formation from isoprene oxidation are only beginning to...
A new model for the formation of secondary organic aerosol (SOA) from isoprene was developed. This model uses surrogate molecular species (hydroxy-hydroperoxides, tetrols, methylglyceric acid, organic...
Stimulated by recent important developments regarding the oxidation chemistry of isoprene, this study evaluates and quantifies the impacts of different mechanism updates on the boundary layer concentr...
Aircraft OH and HO2 measurements made over West Africa during the AMMA field campaign in summer 2006 have been investigated using a box model constrained to observations of long-lived species and phys...
Recently reported model-measurement discrepancies for the concentrations of the HOx radical species (OH and HO2) in locations characterized by high emission rates of isoprene have indicated possible d...
In the 1990s the rates of increase of greenhouse gas concentrations, most notably of methane, were observed to change, for reasons that have yet to be fully determined. This period included the erupti...
Isoprene is an important atmospheric volatile organic compound involved in ozone production and NOx (NO+NO2) sequestration and transport. Isoprene reaction with OH in the presence of NO can form eithe...
A numerical evaluation of global oceanic emissions of α-pinene and isoprene based on both "bottom-up" and "top-down" methods is presented. We infer that the global "bottom-up" oceanic emissions of α-p...
We evaluate the effect of varying the temporal resolution of the input climate data on isoprene emission estimates generated by the community emissions model MEGAN (Model of Emissions of Gases and Aer...
Oxidation of isoprene through reaction with NO3 radicals is a significant sink for isoprene that persists after dark. The main products of the reaction are multifunctional nitrates. These nitrates con...
phytoplankton isoprene production and dynamic euphotic depth to simulate hourly marine isoprene emissions totaling 0.92 Tg C yr−1. Sensitivity studies using different schemes for the euphotic zo...
We examine the dependence of the inferred isoprene surface emission flux from atmospheric concentration on the diurnal variability of the convective boundary layer (CBL). A series of systematic numeri...
Simulations of future tropospheric composition often include substantial increases in biogenic isoprene emissions arising from the Arrhenius-like leaf emission response and warmer surface temperatures...
We present an oxidation mechanism of intermediate size for isoprene (2-methyl-1,3-butadiene) suitable for simulations in regional and global atmospheric chemistry models, which we call MIM2. It is a r...
Formaldehyde (HCHO) is an important intermediate compound in the degradation of volatile organic compounds (VOCs) in the troposphere. Sources of HCHO are largely dominated by its secondary production ...

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