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Experimental quantification of electrostatics in X-H⋅⋅⋅π hydrogen bonds
Experimental quantification electrostatics X-H⋅ ⋅ ⋅ π hydrogen bonds
2016/5/25
Hydrogen bonds are ubiquitous in chemistry and biology. The physical forces that govern hydrogen-bonding interactions have been heavily debated, with much of the discussion focused on the relative con...
Direct Measurements of Electric Fields in Weak OH••π Hydrogen Bonds
Direct Measurements Electric Fields Weak OH• • π Hydrogen Bonds
2016/5/25
Hydrogen bonds and aromatic interactions are of widespread importance in chemistry, biology, and materials science. Electrostatics play a fundamental role in these interactions, but the magnitude of t...
Electrostatic Fields Near the Active Site of Human Aldose Reductase:2.New Inhibitors and Complications Caused by Hydrogen Bonds
Humans Nitriles Aldehyde Reductase Spectrophotometry, Infrared Spectroscopy, Fourier Transform Infrared Binding Sites Catalytic Domain Protein Binding Kinetics Hydrogen Bonding
2016/5/25
Vibrational Stark effect spectroscopy was used to measure electrostatic fields in the hydrophobic region of the active site of human aldose reductase (hALR2). A new nitrile-containing inhibitor was de...